๐Ÿงช 1999

JAMB Chemistry 1999 past questions

48 questions from the 1999 JAMB UTME Chemistry paper. Free, with answers where available.

Chemistry JAMB 1999 Q2 โœ“ Answer: C
Sieving is a technique used to separate mixtures containing solid particles of
A
small sizes
B
large sizes
C
different sizes
D
the same size
Chemistry JAMB 1999 Q3 โœ“ Answer: D
Which of the following gases will diffuse fastest when passed through a porous plug?
A
Propane
B
Oxygen
C
Methane
D
Ammonia [H = 1, C = 12, N= 14, O = 16]
Chemistry JAMB 1999 Q3 โœ“ Answer: C
Which of the compounds is composed of Al, Si, O and H?
A
Epson salt
B
Limestone
C
Clay
D
Urea
Chemistry JAMB 1999 Q4 โœ“ Answer: B
Which of the following will have its mass increased when heated in air?
A
Helium
B
Magnesium
C
Copper pyrites
D
Glass
Chemistry JAMB 1999 Q4 โœ“ Answer: C
50cm3 of carbon (11) oxide was exploded with 150cm3 of air containing 20% oxygen by volume, which of the reactants was in excess?
A
Carbon (11) oxide
B
Carbon (1V) oxide
C
Oxygen
D
Nitrogen
Chemistry JAMB 1999 Q5 โœ“ Answer: A
What is the temperature of a given mass of a gas initially OoC and 9 atm, if the pressure is reduced to 3 [PAGE 54] atmosphere at constant volume?
A
91 K
B
182 K
C
273 K
D
819 K
Chemistry JAMB 1999 Q6 โœ“ Answer: D
In the diagram above, the mixture of the two solid P and Q can be separated by
A
distillation
B
fractional distillation
C
crystallization
D
fractional crystallization.
Chemistry JAMB 1999 Q6 โœ“ Answer: D
The ratio of the initial to the final pressure of a given mass of gas is 1:1:5. Calculate the final volume of the gas if the initial volume was 300cm3 at the same temperature.
A
120 cm3
B
200 cm3
C
450 cm3
D
750 cm3
Chemistry JAMB 1999 Q7 โœ“ Answer: B
Mg(s) + 2HCl (aq) MgCl2(aq) + H2(g). From the equation above, the mass of magnesium required to react with 250cm3 of .5 M HCl is
A
0.3 g
B
1.5 g
C
2.4 g
D
3.0 g [ M = 27, Cl = 35.5]
Chemistry JAMB 1999 Q7 โœ“ Answer: B
The partial pressure of oxygen in a sample of air is 452mm Hg and the total pressure is 780mmHg. What is the mole fraction of oxygen?
A
0.203
B
0.579
C
2.030
D
5.790
Chemistry JAMB 1999 Q8 โœ“ Answer: D
The fundamental difference between the three states of matter is the
A
shape of their particles
B
number of particles in each state
C
shape of the container they occupy
D
degree of movement of their particles
Chemistry JAMB 1999 Q9 โœ“ Answer: D
In which of the following are water molecules in the most disorderly arrangement?
A
Ice at โ€“10oC
B
Ice at OoC
C
Water at 100oC
D
Steam at 100oC
Chemistry JAMB 1999 Q9 โœ“ Answer: B
Which of the following the following statements is correct about the periodic table?
A
Element in the same period have the same number of valence electrons
B
The valence electrons of the elements in the same period increase progressively across the period Chemistry 2000
C
Elements in the same group have the number of electron shells
D
The non-metallic properties of the elements tent to decrease across each period
Chemistry JAMB 1999 Q10 โœ“ Answer: B
In order to remove one electron from 3s-orbital of gaseous sodium atom, about 496 kJ mol-1 of energy is required. This energy is referred to as
A
electron affinity
B
ionization energy
C
activation energy
D
electronegativity
Chemistry JAMB 1999 Q12 โœ“ Answer: C
The method that can be used to convert hard water to soft water is
A
Chlorination B Passage over activated charcoal
C
the use of an ion exchange resin
D
aeration Use the table below to answer question 13 and 14
Chemistry JAMB 1999 Q13 โœ“ Answer: C
The element that is likely to participate in covalent rather than ionic bonding is
A
Z
B
Y
C
X
D
W
Chemistry JAMB 1999 Q14 โœ“ Answer: A
The least reactive elements is
A
W
B
X
C
Y
D
Z
Chemistry JAMB 1999 Q15 โœ“ Answer: C
ls22s22p63s23p63d74s2. An element with the electron configuration above is a
A
non-metal
B
metal
C
transition element
D
group two element
Chemistry JAMB 1999 Q16 โœ“ Answer: A
Given that electronegativity increases across a period and decreases down a group in the periodic table, in which of the following compounds will the molecules be held together by the strongest hydrogen bond?
A
HF(g)
B
NH(g)
C
CH4(g)
D
HCl(g)
Chemistry JAMB 1999 Q17 โœ“ Answer: B
0.25 mole of hydrogen chloride was dissolved in distilled water and the volume made up to 0.50dm3. If 15.00cm3 of the solution requires 12.50 cm3 of aqueous sodium trioxocarbonate (1V0 for neutralization, calculate the concentration of the alkaline solution.
A
0.30 mol dm-3
B
0.40 mol dm-3
C
0.50 mol dm-3
D
0.60 mol dm-3
Chemistry JAMB 1999 Q18 โœ“ Answer: A
The correct order of increasing oxidation number of the transition metal ions for the compounds K2Cr2O7, V2O5 and KmnO4 is
A
V2O5 < K2Cr2O7, < KMnO4
B
K2Cr2O7, < KMnO4 < V2O5
C
KMnO4 < K2Cr2O7, <V2O5
D
KMnO4 < <V2O5 < K2Cr2O7,
Chemistry JAMB 1999 Q19 โœ“ Answer: C
The set of pollutants that is most likely to be produced when petrol is accidentally spilled on plastic materials and ignited is
A
CO, CO2 and SO2
B
CO, HCl and SO2
C
CO, CO2 and HCl
D
SO2, CO2 and HCl
Chemistry JAMB 1999 Q20 โœ“ Answer: D
What is observed when aqueous solution of each of tetraoxosulphate(V1) acid, potassium trioxides (V) and potassium iodine are mixed together?
A
white precipitate is formed
B
a green precipitate is formed
C
The mixture remains colourless
D
The mixture turns reddish-brown.
Chemistry JAMB 1999 Q21 โœ“ Answer: D
From the diagram above, the mass of crystals [PAGE 55] deposited when 1 dm3 of a saturated solution of NaCl is cooled from 80oC to 60oC is
A
117.00 g
B
58.50 g
C
11.70 g
D
5.85 g [Na = 23, Cl = 35.5]
Chemistry JAMB 1999 Q22 โœ“ Answer: A
The solution with the lowest pH value is
A
5 ml of m/n HCl
B
10 ml of m/n HCl
C
15 ml of m/n HCl
D
20 ml of m/n HCl
Chemistry JAMB 1999 Q23 โœ“ Answer: C
The solubility product of Cu(lO3)2 is 1.08 x 10-7. Assuming that neither ions react appreciably with water to form H+ and OH-, what is the solubility of this salt?
A
2.7 x 10-8 mol dm-3
B
9.0 x 10-8 mol dm-3
C
3.0 x 10-8 mol dm-3
D
9.0 x 10-8 mol dm-3
Chemistry JAMB 1999 Q24 โœ“ Answer: A
The entropy and enthalpy of a system are a measure of
A
degree of disorderliness and heat content respectively
B
heat content and degree of disorderliness respectively
C
heat content of a system only
D
degree of disorderliness only.
Chemistry JAMB 1999 Q25 โœ“ Answer: C
2SO2(g) + O2(g) 2NO2(g). In the chemical reaction above, the substance that will increase the rate of production of sulphur (V1) oxide is
A
manganese (1V)oxide
B
finely divided ion
C
vanadium (V0 oxide
D
nickel
Chemistry JAMB 1999 Q27 โœ“ Answer: D
What quantity of electricity will liberate 0.125 mole of oxygen molecules during the electrolysis of dilute sodium chloride solution?
A
24 125 coulombs
B
48 250 coulombs
C
72 375 coulombs
D
96 500 coulombs [F = 96 500C mol-1]
Chemistry JAMB 1999 Q29 โœ“ Answer: B
When a current 1 was passed through an electrolyte solution for 40 minutes, a mass Xg of a univalent metal was deposited at the cathode. What mass of the metal will be deposited when a current 21 is passed through the solution for 10 minutes?
A
x/4 g
B
x/2 g
C
2X g
D
4X g
Chemistry JAMB 1999 Q30 โœ“ Answer: B
RS(aq) + HF (aq) RF(s) + HS(aq) H =-65.7 kJ mol1. From the equation above, it can be deduced that.
A
the heat content of the reactants is lower than that of the reactants ucts
B
the heat content of the reactants is higher than that of the products
C
the reaction is slow
D
a large amount of heat is absorbed.
Chemistry JAMB 1999 Q31 โœ“ Answer: D
Which of the following statements is true of the electrochemical series?
A
Electropositivity of metals increase down the series
B
Electropositivity of non-metals decrease down the series
C
Electronegativity of non-metals increase down the series
D
Electropositivity of metal decreases down the series
Chemistry JAMB 1999 Q32 โœ“ Answer: D
The gas that will form a white precipitate with acidified silver trioxonirate (V) is
A
NH3
B
SO2
C
CO2
D
HCl
Chemistry JAMB 1999 Q33 โœ“ Answer: D
Chlorine bromine and iodine resemble one another in that they
A
dissolve in alkalis
B
react violently with hydrogen without heating
C
are liquids
D
displace one another from solutions of their salts.
Chemistry JAMB 1999 Q34 โœ“ Answer: B
The salt that reacts with dilute hydrochloric which decolourizes acidified purple smelling gas which decolourizes acidified purple potassium tetraoxomanganate(V11) solution is
A
Na2SO4
B
Na2SO3
C
Na2S
D
Na2CO3
Chemistry JAMB 1999 Q36 โœ“ Answer: A
Hydrogen is used in oxy-hydrogen flames for melting metals because it
A
evolves a lot of heat when burnt
B
combines explosively with oxygen
C
is a very light gas
D
is a rocket fuel. [PAGE 56]
Chemistry JAMB 1999 Q37 โœ“ Answer: A
In the diagram above Y is mixture of
A
Calcium hydroxide and ammonium chloride
B
Calcium hydroxide and sodium chloride(V)
C
Sodium chloride and ammonium trioxonirate(V)
D
Sodium dioxonitrate(lll) and ammonium chloride.
Chemistry JAMB 1999 Q38 โœ“ Answer: C
What properties of duralumin make it more useful than its constituent metals?
A
it is heavy with a high melting point
B
it is malleable and has high density
C
it is strong and light
D
it is hard and ductile
Chemistry JAMB 1999 Q39 โœ“ Answer: B
The pair of metals in the reactivity series that are usually extracted by the electrolysis of their ores is
A
Magnesium and zinc
B
Magnesium and calcium
C
Copper and zinc
D
Lead and calcium
Chemistry JAMB 1999 Q41 โœ“ Answer: A
Which of the following metals is passive to concentrated trioxonirate(V) acid?
A
iron
B
tin
C
copper
D
zinc
Chemistry JAMB 1999 Q42 โœ“ Answer: A
The hydrocarbon the burns in air with a sooty flame is
A
C6H6
B
C3H6
C
C4H10
D
C6H6
Chemistry JAMB 1999 Q43 โœ“ Answer: A
2-methylprop-1-ene is an isomer of
A
but-2-ene
B
pent-l-ene
C
2-methylbut-ene
D
2-methylbut-l-ene
Chemistry JAMB 1999 Q45 โœ“ Answer: C
When excess ethanol is heated to 145oC in the presence of concentrated H2SO4 the product is
A
ethyne
B
diethyl sulphate
C
diethyl ether
D
acetone
Chemistry JAMB 1999 Q46 โœ“ Answer: D
How many grammes of bromine will saturate 5.2 g of but-l-ene-3-yne?
A
64.0 g
B
48.0 g
C
32.0 g
D
16.0 g [C = 12, H= 1, Br = 80]
Chemistry JAMB 1999 Q47 โœ“ Answer: D
Polyvinyl chloride is used to produced
A
bread
B
pencils
C
ink
D
pipes
Chemistry JAMB 1999 Q48 โœ“ Answer: A
An organic compound that does not undergo a reaction with both hydrogen cyanide and hydroxylamine can be an
A
alkenes
B
alkanal
C
alkanone
D
Alkanoic acid
Chemistry JAMB 1999 Q49 โœ“ Answer: B
When two end alkyl groups of ethyl ethanoate are interchanged, the compound formed is known as
A
methylethanoate
B
ethyl propionate
C
methylpronoste
D
propel ethanoate.
Chemistry JAMB 1999 Q50 โœ“ Answer: B
Which of the compounds above would react to take up two molecules of bromine during bromination?
A
1 only
B
111 only
C
1 and 11 only
D
11 and 111 only [PAGE 57]