🧪 1993

JAMB Chemistry 1993 past questions

32 questions from the 1993 JAMB UTME Chemistry paper. Free, with answers where available.

Chemistry JAMB 1993 Q9 ✓ Answer: A
An element, E, has the electronic configuration 1s22s22p63s23p3. The reaction of E with a halogen X can give.
A
EX3 and EX5
B
EX3 only
C
EX5 only
D
EX2 and EX3
Chemistry JAMB 1993 Q10 ✓ Answer: C
Two atoms represented as 235 92Uand 238 92U are
A
isomers
B
allotropes
C
isotopes
D
anomers
Chemistry JAMB 1993 Q11 ✓ Answer: B
As the difference in electronegativity between bonded atoms increase, polarity of the bond
A
decreases
B
increases
C
remains unchanged
D
reduces to zero.
Chemistry JAMB 1993 Q13 ✓ Answer: A
Water has a rather high boiling point despite its low molecular mass because of the presence of
A
hydrogen bonding
B
covalent bonding
C
ionic bonding
D
metallic bonding
Chemistry JAMB 1993 Q14 ✓ Answer: D
Argon is used in gas-filled electric lamps because it helps to
A
prevent the reduction of the lamp filament
B
prevent oxidation of lamp filament
C
make lamp filaments glow brightly
D
keep the atmosphere in the lamp inert.
Chemistry JAMB 1993 Q15 ✓ Answer: C
The air around a petroleum refinery is most likely to contain
A
CO2 SO3 and N2O
B
CO2 CO and N2O
C
SO3 CO and NO2
D
PH3 H2O and CO2
Chemistry JAMB 1993 Q16 ✓ Answer: A
Water can be identified by the use of
A
an hydrogen copper(11) tetraoxosulphate(1V)
B
an hydrogen sodium trioxocarbonate(1V)
C
potassium heptaoxochromate(vii)
D
copper (11) trioxocarbonate(iv)
Chemistry JAMB 1993 Q17 ✓ Answer: D
The phenomenon whereby sodium trioxocarbonate (1) decahydrate loses some of its water crystallization on exposure to the atmosphere is known as
A
deliquescence
B
hygroscopy
C
effervescence
D
efflorescence [PAGE 38]
Chemistry JAMB 1993 Q19 ✓ Answer: B
For which salt in the graph above does the solubility increase most rapidly with rise in temperature
A
CaSO4
B
KNO3
C
NaCl
D
KCl
Chemistry JAMB 1993 Q20 ✓ Answer: C
NH3 + H3O NH4 + H2O. it may be deduced from the reaction above that
A
a redox reaction has occurred
B
H3O+ acts as an oxidizing agent
C
H3O+ acts as an acid
D
Water acts as an acid
Chemistry JAMB 1993 Q21 ✓ Answer: A
4.0 g of sodium hydroxide in 250 cm3 of solution contains
A
0.40 moles per dm3
B
0.10 moles per dm3
C
0.04 moles per dm3
D
0.02 moles per dm3
Chemistry JAMB 1993 Q23 ✓ Answer: A
Which of the following reactions occurs at the anode during the electrolysis of a very dilute aqueous solution of sodium chloride?
A
OH –CH OH
B
Cl- - e- Cl
C
OH + Cl- HCl
D
Na+ + e- Na/Hg amalgam Hg
Chemistry JAMB 1993 Q24 ✓ Answer: C
Half – cell reaction E0 Cu2+(aq) + 2e Cu(s) +0.34V Fe2+(aq) + 2e Fe -0.44V Ba2+(aq) + 2e Ba(s) -2.90V Zn2+(aq) + 2e Zn(s) -0.76V From the data above, it can be deduced that the most powerful reducing agent of the four metals is
A
Cu
B
Fe
C
Ba
D
Zn
Chemistry JAMB 1993 Q25 ✓ Answer: D
The oxidation states of chlorine in HOCl, HClO3 and HClO4 are respectively
A
-1, +5 and +7
B
–1 ,-5 and 7
C
+1, +3 and +4
D
+1, +5 and +7
Chemistry JAMB 1993 Q28 ✓ Answer: A
The standard enthalpies of formation of CO2(g), H2O(g) and CO(g) in kJ mol-1 are –394, -242 and –110 respectively. What is the standard enthalpy change for the reaction CO(g) + H2O CO2(g) + H2(g)?
A
-42 kJ mol-1
B
+42 kJ mol-1
C
–262 kJ mol-1
D
+262 kJ mol-1
Chemistry JAMB 1993 Q29 ✓ Answer: A
10 g of a solid is in equilibrium with its own vapour. When 1 g of a small amount of solid is added, the vapour pressure
A
remain the same
B
drops
C
increase by 1%
D
increase by 99%
Chemistry JAMB 1993 Q30 ✓ Answer: C
In the diagram above, curve X represents the energy profile for a homogeneous gaseous reaction. Which of the following conditions would produce curve Y for the same reaction?
A
increase in temperature
B
increase in the concentration of a rectant
C
addition of a catalyst
D
increase in pressure.
Chemistry JAMB 1993 Q31 ✓ Answer: D
NaCl(s) + H2SO4(1) HCl(g) + NaHSO4(s). In the reaction above. H2SO4 behaves as
A
a stron acid
B
an oxiding agent
C
a good solvent
D
a dehydrating agent. [PAGE 39]
Chemistry JAMB 1993 Q32 ✓ Answer: A
Which of these salts will produce its metal, oxygen and nitrogen(1V) oxide on heating?
A
Silver trioxonitrate(V)
B
Sodium trioxonitrate (V)
C
Calcium trioxonitrate (V)
D
Lithium trioxonitrate (V)
Chemistry JAMB 1993 Q33 ✓ Answer: A
An experiment produces a gaseous mixture of carbon (1V) oxide and carbon(11) Oxide. In order to obtain pure carbon (11) oxide, the gas mixture should be
A
passed over heated copper(11) oxide
B
bubbled through concentrated tetraoxosulphate(V1) acid
C
bubbled through sodium hydroxide solution
D
bubbled through water.
Chemistry JAMB 1993 Q34 ✓ Answer: B
Which of the following is property of ionic chlorides?
A
They can be decomposed heat.
B
They react with aqueous AgNO3 to give q white precipitate which is soluble in excess ammonia
C
They explode when in contact with dry ammonia gas
D
They react with concentrated tetraoxosulphate (V1) acid to give white fumes of chlorides gas
Chemistry JAMB 1993 Q35 ✓ Answer: D
When dilute aqueous solutions of (11) nitrate and potassium bromide are mixed, a precipitate is observed. The products of this reaction are.
A
PbO(s) + Br- (aq) + KNO3
B
Br2 + NO2(g) + PbBr2(s)
C
PbO(s) PbO(s) + K+(aq) + Br(aq) +NO2(g)
D
PbBr2(s) + K+(aq) + NO3(aq)
Chemistry JAMB 1993 Q36 ✓ Answer: D
Bronze is an alloy will react to
A
Silver and copper
B
Silver and gold
C
Copper and nickel
D
Copper and zinc
Chemistry JAMB 1993 Q37 ✓ Answer: D
Copper metal will react with concentrated trioxonitrate (V) acid to give
A
Cu(NO3)3 + NO + N2O4 + H2O
B
Cu(NO3)2 + NO + H2O
C
CuO +NO2 + H2O
D
Cu(NO3)2 + NO2 + H2O
Chemistry JAMB 1993 Q38 ✓ Answer: C
The active reducing agent in the blast furnace for the extraction of iron is
A
carbon
B
limestone
C
carbon (11) oxide
D
calcium oxide
Chemistry JAMB 1993 Q39 ✓ Answer: B
Al2O3(s) + 3H2SO4(aq)=Al2(SO4)3(aq) + 3H2O(1) Al2O3(s) + 2NaOH(aq) + 3H2O (1) ’! 2NaAl(OH)4(aq). We can conclude from the equations above that Al2O3(s) is
A
an acidic oxide
B
an amphoteric oxide
C
a basic oxide
D
a neutral oxide
Chemistry JAMB 1993 Q41 ✓ Answer: C
The fraction of crude oil used as jet fule is
A
refinery gas
B
diesel oil
C
kerosene
D
gasoline
Chemistry JAMB 1993 Q42 ✓ Answer: D
CH3CHCH2CHCH2CH3 CH3 CH3. The IUPAC nomenclature for the compound above is.
A
dimethylhexane
B
3,5 dimethlpentane
C
1,1 dimethyl , 3 methylpentane
D
2,4 dimethylhexane.
Chemistry JAMB 1993 Q43 ✓ Answer: B
It is not desirable to use lead tetraethyl as an anti- knock agent because
A
it is expensive
B
of pollution effects from the exhaust fumes
C
it lowers the octane rating of petrol
D
it is explosive.
Chemistry JAMB 1993 Q44 ✓ Answer: B
The carbon atoms on ethane are
A
sp2 hybridized
B
sp3 hybridized
C
sp2d hybridized
D
sp hybridized.
Chemistry JAMB 1993 Q46 ✓ Answer: A
O O CH3 C-OCH2CH2 and CH3CH2CH2 C-OH are
A
isomers
B
esters
C
carboxylic acids
D
polymers.
Chemistry JAMB 1993 Q47 ✓ Answer: D
Palm wine turns sour with time because.
A
the sugar content is converted into alcohol
B
the carbon(1V) oxide formed during the fermentation process has a sour taste
C
it is commonly adulterated by the tappers and sellers
D
microbial activity results in the production of organic acids within it. [PAGE 40] The function of the copper (11) tetraoxosulphate (V1) in dilute H2SO4 in the figure above is to